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13The hydrothermal reaction of V2O5, V2O3, 2,2′-bpy and Na2SO4 in dilute sulfuric acid yields a novel hybrid, [VIVO]∞, which demonstrates the potential of constructing a new class of robust composite solids composed of a {V/O/SO4}-based framework decorated with organic functionalities by combining appropriate vanadyl sulfate motifs with a variety of organic ligands.
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6The solvothermal reaction of 3N with [4N]3[H3V 10O28] and MnCl2·4H2O in CH3CN and CH3OH yields a novel cationic heteropolyoxovanadium cluster, [MnIIVIV6O6{2N}6] 2+, containing a fully reduced new cyclic {MnV6N6O18} core with the Anderson structure.