Olimpia Lombardi

One of the main ontological challenges posed by quantum mechanics is the problem of the indistinguishability of so-called “identical” particles, that is, particles that share the same state-independent properties. In the framework of this philosophical problem, a quasi-set theory was formulated to provide a proper metalanguage to deal with quantum indistinguishability; this theory included certain Urelemente called m-atoms, representing essentially indistinguishable objects. In turn, over the last two decades, the Modal Hamiltonian Interpretation proposed an ontology of properties, totally devoid of objects, where quantum systems are bundles of instances of universal properties. Therefore, the original quasi-set theory, with its m-atoms, does not adequately reflect the structure of an ontology devoid of objects. The purpose to the present article is to introduce a new quasi-set theory that does not include atoms at all: elementary items correspond to properties and are also represented by quasi-sets, which can be only numerically different. The final aim is to apply this new quasi-set theory to the MHI ontology.

Although Bohr’s Correspondence Principle (CP) played a central role in the first days of quantum mechanics, its original version seems to have no present-day relevance. The purpose of this article is to show that the CP, with no need of being interpreted in terms of the quantum-to-classical limit, still plays a relevant role in the understanding of the relationships between the classical and the quantum domains. In particular, it will be argued that a generic version of the CP is very helpful in elucidating the physical meaning of the phenomenon of quantum decoherence.

Some authors, inspired by the theoretical requirements for the formulation of a quantum theory of gravity, proposed a relational reconstruction of the quantum parameter-time—the time of the unitary evolution, which would make quantum mechanics compatible with relativity. The aim of the present work is to follow the lead of those relational programs by proposing a relational reconstruction of the event-time—which orders the detection of the definite values of the system’s observables. Such a reconstruction will be based on the modal-Hamiltonian interpretation of quantum mechanics, which provides a clear criterion to select which observables acquire a definite value and to specify in what situation they do so.

Although the electron density can be calculated with the formal resources of quantum mechanics, in physics it does not play the leading role that the quantum state does. In contrast, the concept of electron density is central in quantum chemistry. There is no doubt about how the electron density is computed in terms of the wave function of an atom or molecule. However, when the interpretation of the concept is at stake, there is no general agreement. In this article we will analyze the two main interpretations of the concept of electron density: the Born-style probability density interpretation and the Schrödinger-style charge density interpretation. In particular, we will examine their differences, their relations with quantum mechanics and the consequences that each of them entails from a strictly quantum point of view.

In a recent article entitled “The problem of molecular structure just is the measurement problem”, Alexander Franklin and Vanessa Seifert argue that insofar as the quantum measurement problem is solved, the problems of molecular structure are resolved as well. The purpose of the present article is to show that such a claim is too optimistic. Although the solution of the quantum measurement problem is relevant to how the problem of molecular structure is faced, such a solution is not sufficient to account for the structure of molecules as understood in the field of chemistry.

El objetivo del presente trabajo es contribuir a la discusión epistemológica acerca de la Teoría del Caos. Nos concentramos en el problema de la definición de caos, argumentando que impredictibilidad y aleatoriedad algorítmica no constituyen una base satisfactoria para definir el caos. El análisis de las diferentes manifestaciones del caos nos permite considerar el problema de encontrar una definición de caos única y adecuada -una definición que brinde condiciones necesarias y suficientes válidas para todas los casos. Sostenemos que, dado el carácter matemático de la temía, la definición debe extraerse a partir de las características de las ecuaciones caóticas.

The concept of molecular structure is one of the most important concepts of chemistry. In fact, molecular structure is closely related to the concept of chemical substance and its set of properties, and it is the main factor in the explanation of reactivity. In fact, much of the behavior of substances is explained in terms of the structure of their component molecules. This may explain why people tend to take the notion of molecular structure for granted. However, the problem begins already when it comes to specifying the concept, since there is no clear definition of ‘molecular structure’ valid for all chemistry. The purpose of the present article is to show that the term ‘molecular structure’ subsumes very different notions, which depend on how the molecule and its components are conceived, and each of which brings its own difficulties. In particular, we will focus on how the molecule and its structure are devised from a classical view and from a quantum–mechanical view, and will discuss the different problems related with molecular structure that arise in each case.

To which ontological category do quantum systems belong? Although we usually speak of particles, it is well known that these peculiar items defy several traditional metaphysical principles. In the present chapter these challenges will be discussed in the light of certain distinctions usually not taken into account in the debate about the ontological nature of quantum systems. On this basis, it will be argued that an ontology of properties without individuals, framed in the algebraic formalism of quantum mechanics, provides adequate answers to the ontological challenges raised by the theory.What kind of item is a quantum system? In the practice of physics it is common to speak of quantum particles, as if they were items of a similar nature to classical items, but obeying different laws of motion. However, as is well known, quantum systems have such peculiar features that they challenge certain ontological principles and categories as understood in traditional metaphysics. In general, these features are analyzed in the context of the so-called problem of indistinguishability, which is a consequence of the particular statistical behavior of quantum systems. But the fact that certain items are “indistinguishable” is not the only difficulty to be overcome in order to elucidate the ontological category of quantum systems.

After the preeminence of logical positivism/empiricism during the most part of twentieth century, during the last decades many authors began to recognize the relevance of the Kantian thought for present-day philosophy of science. This chapter follows this general trend, adopting a realist reading of Kantian teachings. On this basis, I will delineate a Kantian-rooted realism according to which the worlds of science are always the result of a synthesis between the conceptual schemes embodied in scientific theories and practices and the independent noumenal reality. However, my position takes distance from the Kantian doctrine by admitting the possibility of different conceptual schemes, both diachronically and synchronically. This view not only leaves room for abrupt and discontinuous changes in the history of science, but also leads to an ontological pluralism that allows for the coexistence of irreducible and different, even incompatible ontological domains at the same historical time. I will focus particularly on the synchronic case to reject both ontological reductionism and emergentism from a perspective that denies any priority or dependence between domains, in resonance with a non-hierarchical articulation between scientific theories and disciplines.

En este artículo se argumenta que la existencia de leyes invariantes frente a inversión temporal no es condición indispensable para la existencia de la flecha del tiempo. Esta última puede definirse como una propiedad global y geométrica del espacio-tiempo que no se basa en consideraciones entrópicas ni requiere de la existencia de leyes no invariantes frente a la inversión temporal. A su vez, si el espacio-tiempo cumple ciertas condiciones, la flecha global se traslada a los contextos locales como un flujo tetradimensional de energía que apunta en la misma dirección temporal en todos los puntos espacio-temporales.

In the literature on the interpretation of quantum mechanics, not many works attempt to adopt a proactive perspective aimed at seeing how different interpretations can enrich each other through a productive dialogue. In particular, few proposals have been devised to show that different approaches can be clarified by comparing them, and can even complement each other, improving or leading to a more fertile overall approach. The purpose of this paper is framed within this perspective of complementation and mutual enrichment. In particular, the Relational Quantum Mechanics and the Modal-Hamiltonian Interpretation are compared, highlighting their differences and points of contact. The final purpose is to show that, in spite of their disagreements, they are not contradictory but, on the contrary, they can be made compatible from an overarching perspective and can even complement each other in a fruitful way.

The main aim of this work is to contribute tothe elucidation of the concept of informationby comparing three different views about thismatter: the view of Fred Dretske's semantictheory of information, the perspective adoptedby Peter Kosso in his interaction-informationaccount of scientific observation, and thesyntactic approach of Thomas Cover and JoyThomas. We will see that these views involvevery different concepts of information, eachone useful in its own field of application. This comparison will allow us to argue in favorof a terminological `cleansing': it is necessaryto make a terminological distinction among thedifferent concepts of information, in order toavoid conceptual confusions when the word`information' is used to elucidate relatedconcepts as knowledge, observation orentropy

By moving away from the traditional reductionist reading of the quantum theory of atoms in molecules, in this paper we analyze the role played by QTAIM in the relationship between molecular chemistry and quantum mechanics from an emergentist perspective. In particular, we show that such a relationship involves two steps: an intra-domain emergence and an inter-domain emergence. Intra-domain emergence, internal to quantum mechanics, results from the fact that the electron density, from which all the other QTAIM’s concepts are defined, arises from the wavefunction as a coarse-grained magnitude. Inter-domain emergence involves an analogical link, a mapping, between QTAIM’s entities, such as topological atoms and bond paths, and the entities that populate the molecular-chemistry domain, such as chemical atoms and chemical bonds.

El objetivo del presente artículo es proponer una nueva interpretación del concepto de información en contextos comunicacionales: una interpretación físicocausal. Apelando a las teorías manipulabilistas de la causación, principalmente en su versión intervencionista, buscaremos mostrar que la información comunicacional es una propiedad física que podemos manipular para generar situaciones comunicacionales. Este enfoque nos permite entender la naturaleza de la comunicación como estructura causal, puesta de manifiesto mediante criterios manipulabilistas. Confiamos en que el enfoque propuesto logra superar ciertas dificultades de las interpretaciones de la información actualmente vigentes en la literatura.

In the problem of the relationship between chemistry and physics, many authors take for granted the ontological reduction of the chemical world to the world of physics. The autonomy of chemistry is usually defended on the basis of the failure of epistemological reduction: not all chemical concepts and laws can be derived from the theoretical framework of physics. The main aim of this paper is to argue that this line of argumentation is not strong enough for eliminate the idea of a hierarchical dependence of chemistry with respect to physics. The rejection of the secondary position of chemistry and the defense of the legitimacy of the philosophy of chemistry require a radically different philosophical perspective that denies not only epistemological reduction but also ontological reduction. Only on the basis of a philosophically grounded ontological pluralism it is possible to accept the ontological autonomy of the chemical world and, with this, to reverse the traditional idea of the ‘superiority’ of physics in the context of natural sciences.

In this work we will deal only with the concept of information in the communicational context, in which information is primarily something that has to be transmitted for communication purposes. The aim of the paper is to consider some arguments traditionally put forward to support the idea that quantum information is qualitatively different than classical information. On the basis of the analysis of those arguments, we will conclude that there are no reasons to admit the existence of quantum information as qualitatively different from classical information: there is only one kind of information, physically neutral, which can be encoded by means of classical or of quantum states.