Charlotte Sophie Werndl

Gibbsian statistical mechanics (GSM) is the most widely used version of statistical mechanics among working physicists. Yet a closer look at GSM reveals that it is unclear what the theory actually says and how it bears on experimental practice. The root cause of the difficulties is the status of the Averaging Principle, the proposition that what we observe in an experiment is the ensemble average of a phase function. We review different stances toward this principle, and eventually present a coherent interpretation of GSM that provides an account of the status and scope of the principle.

Entropy is ubiquitous in physics, and it plays important roles in numerous other disciplines ranging from logic and statistics to biology and economics. However, a closer look reveals a complicated picture: entropy is defined differently in different contexts, and even within the same domain different notions of entropy are at work. Some of these are defined in terms of probabilities, others are not. The aim of this chapter is to arrive at an understanding of some of the most important notions of entropy and to clarify the relations between them, After setting the stage by introducing the thermodynamic entropy, we discuss notions of entropy in information theory, statistical mechanics, dynamical systems theory and fractal geometry

This paper reviews some major episodes in the history of the spatial isomorphism problem of dynamical systems theory. In particular, by analysing, both systematically and in historical context, a hitherto unpublished letter written in 1941 by John von Neumann to Stanislaw Ulam, this paper clarifies von Neumann's contribution to discovering the relationship between spatial isomorphism and spectral isomorphism. The main message of the paper is that von Neumann's argument described in his letter to Ulam is the very first proof that spatial isomorphism and spectral isomorphism are not equivalent because spectral isomorphism is weaker than spatial isomorphism: von Neumann shows that spectrally isomorphic ergodic dynamical systems with mixed spectra need not be spatially isomorphic.

The received wisdom in statistical mechanics is that isolated systems, when left to themselves, approach equilibrium. But under what circumstances does an equilibrium state exist and an approach to equilibrium take place? In this paper we address these questions from the vantage point of the long-run fraction of time definition of Boltzmannian equilibrium that we developed in two recent papers. After a short summary of Boltzmannian statistical mechanics and our definition of equilibrium, we state an existence theorem which provides general criteria for the existence of an equilibrium state. We first illustrate how the theorem works with a toy example, which allows us to illustrate the various elements of the theorem in a simple setting. After a look at the ergodic programme, we discuss equilibria in a number of different gas systems: the ideal gas, the dilute gas, the Kac gas, the stadium gas, the mushroom gas and the multi-mushroom gas. In the conclusion we briefly summarise the main points and highlight open questions.

Gases reach equilibrium when left to themselves. Why do they behave in this way? The canonical answer to this question, originally proffered by Boltzmann, is that the systems have to be ergodic. This answer has been criticised on different grounds and is now widely regarded as flawed. In this paper we argue that some of the main arguments against Boltzmann's answer, in particular, arguments based on the KAM-theorem and the Markus-Meyer theorem, are beside the point. We then argue that something close to Boltzmann's original proposal is true for gases: gases behave thermodynamic-like if they are epsilon-ergodic, i.e., ergodic on the entire accessible phase space except for a small region of measure epsilon. This answer is promising because there are good reasons to believe that relevant systems in statistical mechanics are epsilon-ergodic

In engineering, as in other scientific fields, researchers seek to confirm their models with real-world data. It is common practice to assess models in terms of the distance between the model outputs and the corresponding experimental observations. An important question that arises is whether the model should then be ‘tuned’, in the sense of estimating the values of free parameters to get a better fit with the data, and furthermore whether the tuned model can be confirmed with the same data used to tune it. This dual use of data is often disparagingly referred to as ‘double-counting’. Here, we analyse these issues, with reference to selected research articles in engineering. Our example studies illustrate more and less controversial practices of model tuning and double-counting, both of which, we argue, can be shown to be legitimate within a Bayesian framework. The question nonetheless remains as to whether the implied scientific assumptions in each case are apt from the engineering point of view

Consider a gas confined to the left half of a container. Then remove the wall separating the two parts. The gas will start spreading and soon be evenly distributed over the entire available space. The gas has approached equilibrium. Why does the gas behave in this way? The canonical answer to this question, originally proffered by Boltzmann, is that the system has to be ergodic for the approach to equilibrium to take place. This answer has been criticised on different grounds and is now widely regarded as flawed. In this paper we argue that these criticisms have dismissed Boltzmann’s answer too quickly and that something almost like Boltzmann’s answer is true: the approach to equilibrium takes place if the system is epsilon-ergodic, i.e. ergodic on the entire accessible phase space except for a small region of measure epsilon. We introduce epsilon-ergodicity and argue that relevant systems in statistical mechanics are indeed espsilon-ergodic.

A gas prepared in a non-equilibrium state will approach equilibrium and stay there. An influential contemporary approach to Statistical Mechanics explains this behaviour in terms of typicality. However, this explanation has been criticised as mysterious as long as no connection with the dynamics of the system is established. We take this criticism as our point of departure. Our central claim is that Hamiltonians of gases which are epsilon-ergodic are typical with respect to the Whitney topology. Because equilibrium states are typical, we argue that there follows the desired conclusion that typical initial conditions approach equilibrium and stay there